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Enhanced Light Absorption in All‐Polymer Biomimetic Photonic Structures by Near‐Zero‐Index Organic Matter
Author(s) -
Castillo Miguel A.,
EstévezVarela C.,
Wardley William P.,
Serna R.,
PastorizaSantos I.,
NúñezSánchez S.,
LopezGarcia Martin
Publication year - 2022
Publication title -
advanced functional materials
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 6.069
H-Index - 322
eISSN - 1616-3028
pISSN - 1616-301X
DOI - 10.1002/adfm.202113039
Subject(s) - materials science , photonics , nanostructure , optoelectronics , photonic crystal , absorption (acoustics) , refractive index , photonic metamaterial , high refractive index polymer , structural coloration , nanotechnology , composite material
Natural photosynthetic photonic nanostructures can show sophisticated light–matter interactions including enhanced light absorption by slow light even for highly pigmented systems. Beyond fundamental biology aspects, these natural nanostructures are very attractive as blueprints for advanced photonic devices. But the soft‐matter biomimetic implementations of such nanostructures is challenging due to the low refractive index contrast of most organic photonic structures. Excitonic organic materials with near‐zero index (NZI) optical properties allow overcoming these bottlenecks. Here, it is demonstrated that the combination of NZI thin films with photonic multilayers like the ones found in nature enables broadband tunable strong reflectance as well as slow light absorption enhancement and tailored photoluminescence properties in the full VIS spectrum. Moreover, it is shown that this complex optical response is tunable, paving the way toward the development of active devices based on all‐polymer and near‐zero index materials photonic structures.