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New random copolymers of phenylsilyl- and alkoxy-substituted phenylenevinylene, DMPS(9)-MEH(1)-PPV, DMPS(5)-MEH(5)-PPV and DMPS(1)-MEH(9)-PPV, have been synthesized by the Gilch dehydrohalogenation route, and thelight-emitting properties of these polymers have been studied. The synthesized polymers were completely solublein common organic solvents, and exhibited good thermal stability, almost up to 380℃. They showed UV-visibleabsorbance and photoluminescence (PL) in the ranges of 422-510 and 513-590 nm, respectively, according to theirfeed ratios. Electroluminescent devices were fabricated with these polymers as emitting layers, and ITO and Al asanode and cathode, respectively. DMPS(1)-MEH(9)-PPV, DMPS(5)-MEH(5)-PPV and DMPS(9)-MEH(1)-PPV exhibitedEL emission maxima at 575 nm, 565 nm, and 541 nm, respectively

Synthesis and Light-emitting Properties of Random Copolymers Composed of Phenylsilyl- and Alkoxy-Sustituted Phenylenevinylene