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Small organic molecules, such as C2H, HCN, and H2CO, are tracers of the C, N,and O budget in protoplanetary disks. We present high angular resolution (10-50au) observations of C2H, HCN, and H2CO lines in five protoplanetary disks fromthe Molecules with ALMA at Planet-forming Scales (MAPS) ALMA Large Program. Wederive column density and excitation temperature profiles for HCN and C2H, andfind that the HCN emission arises in a temperate (20-30 K) layer in the disk,while C2H is present in relatively warmer (20-60 K) layers. In the case of HD163296, we find a decrease in column density for HCN and C2H inside one of thedust gaps near 83 au, where a planet has been proposed to be located. We deriveH2CO column density profiles assuming temperatures between 20 and 50 K, andfind slightly higher column densities in the colder disks around T Tauri starsthan around Herbig Ae stars. The H2CO column densities rise near the locationof the CO snowline and/or millimeter dust edge, suggesting an efficient releaseof H2CO ices in the outer disk. Finally, we find that the inner 50 au of thesedisks are rich in organic species, with abundances relative to water that aresimilar to cometary values. Comets could therefore deliver water and keyorganics to future planets in these disks, similar to what might have happenedhere on Earth. This paper is part of the MAPS special issue of theAstrophysical Journal Supplement.

Molecules with ALMA at Planet-forming Scales (MAPS) VI: Distribution of the small organics HCN, C2H, and H2CO