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We investigated the influence of two fillers-CB (carbon black) and silica-on the H 2 permeation of EPDM polymers crosslinked with sulfur in the pressure ranges 1.2-90 MPa. H 2 uptake in the CB-blended EPDM revealed dual sorption (Henry's law and Langmuir model) when exposed to pressure. This phenomenon indicates that H 2 uptake is determined by the polymer chain and filler-surface absorption characteristics. Moreover, single sorption characteristics for neat and silica-blended EPDM specimens obey Henry's law, indicating that H 2 uptake is dominated by polymer chain absorption. The pressure-dependent diffusivity for the CB-filled EPDM is explained by Knudsen and bulk diffusion, divided at the critical pressure region. The neat and silica-blended EPDM specimens revealed that bulk diffusion behaviors decrease with decreasing pressure. The H 2 diffusivities in CB-filled EPDM composites decrease because the impermeable filler increases the tortuosity in the polymer and causes filler-polymer interactions; the linear decrease in diffusivity in silica-blended EPDM was attributed to an increase in the tortuosity. Good correlations of permeability with density and tensile strength were observed. From the investigated relationships, it is possible to select EPDM candidates with the lowest H 2 -permeation properties as seal materials to prevent gas leakage under high pressure in H 2 -refueling stations.

polymers

H2 Uptake and Diffusion Characteristics in Sulfur-Crosslinked Ethylene Propylene Diene Monomer Polymer Composites with Carbon Black and Silica Fillers after High-Pressure Hydrogen Exposure Reaching 90 MPa