English (United Kingdom)

https://curated-unify.zendy.io/wp-json/zendy-region/v1/featured_content/oa?rat=en

https://curated-unify.zendy.io/wp-json/zendy-region/v1/highlighted_journal/

Global: Zendy Plus annual

Presents the access of premium content as premium feature

Premium Content

Presents the keyphrase highlighting as premium feature

Keyphrase Highlighting

Presents the summarisation as premium feature

Summarisation

Insights

Presents the pdf analysis as premium feature

PDF Analysis

Presents the zaia usage as premium feature

ZAIA

Global: Zendy Plus monthly

Global: Zendy Tools annual

Global: Zendy Tools monthly

Global: Zendy Free Plan

The influence of hydrogen on the fracture toughness and fatigue crack propagation rate of two structural steel grades, with and without vanadium, was evaluated by means of tests performed on thermally precharged samples in a hydrogen reactor at 195 bar and 450 °C for 21 h. The degradation of the mechanical properties was directly correlated with the interaction between hydrogen atoms and the steel microstructure. A LECO DH603 hydrogen analyzer was used to study the activation energies of the different microstructural trapping sites, and also to study the hydrogen eggresion kinetics at room temperature. The electrochemical hydrogen permeation technique was employed to estimate the apparent hydrogen diffusion coefficient. Under the mentioned hydrogen precharging conditions, a very high hydrogen concentration was introduced within the V-added steel (4.3 ppm). The V-added grade had stronger trapping sites and much lower apparent diffusion coefficient. Hydrogen embrittlement susceptibility increased significantly due to the presence of internal hydrogen in the V-free steel in comparison with tests carried out in the uncharged condition. However, the V-added steel grade (+0.31%V) was less sensitive to hydrogen embrittlement. This fact was ascribed to the positive effect of the precipitated nanometric (Mo,V)C to alleviate hydrogen embrittlement. Mixed nanometric (Mo,V)C might be considered to be nondiffusible hydrogen-trapping sites, in view of their strong hydrogen-trapping capability (~35 kJ/mol). Hence, mechanical behavior of the V-added grade in the presence of internal hydrogen was notably improved.

The Positive Role of Nanometric Molybdenum–Vanadium Carbides in Mitigating Hydrogen Embrittlement in Structural Steels