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اصطناع بوليميرات آزو ببلمرة مشتاقات إيتيرية لبروميد الآليل ودراسة فجوتها الطاقية وتعيين بعض خصائصها الفيزيائية
Author(s) -
غازي محمود حسو جاويش,
رشدي مدور,
فرانسوا قره بت
Publication year - 2021
Publication title -
مجلة العلوم الطبيعية و الحياتية والتطبيقية
Language(s) - English
Resource type - Journals
ISSN - 2522-3356
DOI - 10.26389/ajsrp.z240721
Subject(s) - chemistry
In this research, two ether derivatives of phenolic azo dyes were synthesized via Williamson's reaction according to the SN2 mechanism. The prepared compounds were radically polymerized using (AIBN) as an initiator and their structures were identified by FT-IR and 1H-NMR. Furthermore, thermal properties of these polymers was made by (DSC). Bandgap energy have been calculated to indicate the ability of these polymers as optical semiconductors, it was 2.8ev, 2.4ev for P(AO2) and P(AON1) respectively. Beside the determination of refractive index, kinematic viscosity, density, and degree of Turbidity.

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