Open AccessSimultaneous correlation of VLE, He and Cpe of some diether + n-alkane systems by the Kohler polynomial
Author(s) -
Mirjana Lj. Kijevčanin,
Slobodan P. Šerbanović,
Ivona R. Radović,
Bojan D. Djordjević,
A. Tasić
Publication year - 2006
Publication title -
journal of the serbian chemical society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.227
H-Index - 45
eISSN - 1820-7421
pISSN - 0352-5139
DOI - 10.2298/jsc0607807k
Subject(s) - alkane , thermodynamics , polynomial , correlation coefficient , work (physics) , equation of state , cubic function , mathematics , correlation , chemistry , physics , mathematical analysis , hydrocarbon , organic chemistry , geometry , statistics
The simultaneous correlation of VLE and excess properties (HE, cPE) for diether + n-alkane systems was performed in our previous paper by the cubic equation of state which incorporates the activity coefficient model (CEOS/GE).With the same aim, in the present work, a completely different approach based on a polynomial equation (Kohler model) was considered. This method gave results on the same systems which could be estimated as being comparable to GEOS/GE models for the simultaneous correlation of two and with considerably improved fits, of three properties.