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The paper presents a research of dependence of adsorption of different ions on a titanium dioxide surface on the pH medium. Equations describing the dependence are presented. It is offered to describe the dependence by means of the acid-base equilibrium that arises on border of TiO2 electrolytic solution phases. It is found that the value of ion adsorption depends on pH. Optimum рН values which were obtained in the course of experiments are presented.