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C 7 H 12.50 Br 1.50 NO, monoclinic,  C 12/ c 1 (no. 15),  a  = 22.249(2) Å,  b  = 8.571(1) Å,  c  = 11.083(1) Å, β = 117.037(8)°,  V  = 1882.5 Å 3 ,  Z  = 8,  R  gt  (F)  = 0.043,  wR  ref  (F  2  )  = 0.116,  T  = 293 K.

Crystal structure of (2RS)-2-bromomethyl-4,4-dimethyl-3,4-dihydro- 2H-pyrrole 1-oxide hemi(hydrobromide), C 7 H 12 BrNO · ½HBr