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Al 23 Co 10.14 Si 8.72 , orthorhombic,  Pnma  (no. 62),  a  = 13.852(3) Å,  b  = 23.055(5) Å,  c  = 7.340(2) Å,  V  = 2344.1 Å 3 ,  Z  = 4,  R  gt  (F)  = 0.035,  wR  ref  (F  2  )  = 0.081,  T  = 293 K.

Crystal structure of cobalt aluminum silicide, Co 10+x Al 23 Si 9 –2x (x = 0.14), the φ phase in the Co-Al-Si system