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C 2 H 3 N 6 NaO, monoclinic,  P 12 1 / m 1 (no. 11),  a =  3.6146(8) Å,  b  = 7.146(1) Å,  c  = 11.258(2) Å, β = 92.02(1)°,  V  = 290.6 Å 3 ,  Z  = 2,  R  gt  (F)  = 0.042,  wR  ref  (F  2  )  = 0.110,  T  = 233 K.

Crystal structure of sodium 4-azido-1,2,3-triazolide monohydrate, Na(N 3 C 2 HN 3 ) · H 2 O