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C 11 H 15 N 2 O 5 P, orthorhombic,  P 2 1 2 1 2 1  (no. 19),  a  = 5.5442(6) Å,  b  = 8.3603(4) Å,  c  = 27.427(3) Å,  V  = 1271.3 Å3,  Z  = 4,  R  gt  (F)  = 0.053,  wR  ref  (F  2  )  = 0.146,  T  = 293 K.

Crystal structure of L-tryptophanium phosphite, (C 11 H 13 N 2 O 2 )[H 2 PO 3 ]