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C 22 H 16 CuN 2 O 5 S 2 , monoclinic,  P 12 1 / c 1 (no. 14),  a  = 8.4228(4) Å,  b  = 19.7169(7) Å,  c  = 12.4746(5) Å, β = 91.041(2)°,  V  = 2071.3 Å 3 ,  Z  = 4,  R  gt  (F)  = 0.067,  wR  ref  (F  2  )  = 0.199,  T  = 295 K.

Crystal structure of aqua(1,10-phenanthroline)bis(2-thiophenecarboxylato) copper(II), Cu(H 2 O)(C 12 H 8 N 2 )(C 4 H 3 SCOO) 2