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C 25 H 22 OS, monoclinic,  P 12 1 1 (no. 4),  a  = 9.679(2) Å,  b  = 13.663(2) Å,  c  = 15.348(2) Å, β = 106.233(5)°,  V  = 1948.7 Å 3 ,  Z  = 4,  R  gt  (F)  = 0.047,  wR  ref  (F  2  )  = 0.119,  T  = 210 K.

Crystal structures of cis- and trans-4-benzyl-4-methyl- 2,6-diphenyl-4H-thiopyran-1-oxide, C 25 H 22 OS