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C 6 H 7 BrClN, orthorhombic,  Pca 2 1  (no. 29),  a  = 16.187(5) Å,  b  = 5.409(5) Å,  c  = 8.992(5) Å,  V  = 787.3 Å 3 ,  Z  = 4,  R  gt  (F)  = 0.041,  wR  ref  (F  2  )  = 0.072,  T  = 293 K.

Crystal structure of o-chloroaniline hydrobromide, (ClC 6 H 4 NH 3 )Br