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Cr 2 O 7 Rb 2 , triclinic,  P 1̅ (No. 2),  a  = 7.433(1) Å,  b  = 7.571(2) Å,  c  = 7.832(2) Å, α = 109.44(3)°, β = 90.81(3)°, γ = 108.89(3)°,  V  = 389.6 Å 3 ,  Z  = 2,  R  gt  (F)  = 0.028,  wR  ref  (F  2  )  = 0.076,  T  = 293 K.

Crystal structure of dirubidium dichromate(VI), Rb 2 Cr 2 O 7 , a fourth polymorph