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The rotational Zeeman effect has been observed in methanimine which was produced from ethylenediamine by flash pyrolysis. The observed vibronic ground state expectation values of the molecular g-values, the magnetic susceptibility anisotropies and the molecular electric quadrupole moments are: g aa  = -1.27099(22), g bb = -0.18975(7), g cc = -0.03440(8), 2ξ aa -ξ bb -ξ cc  = 12.49(19) · 10 -6  ergG -2 mol -1 , 2ξ bb -ξ cc -ξ aa  = 5.22(11) · 10 -6  ergG -2  mol -1  Q aa  = 0.43(17) · 10 -26 esu cm 2 , Q bb = 1.08(10) · 10 -26  esu cm 2 , and Q cc = -1.51 (26) . 10 -26  esu cm 2 . With the TZVP ab initio value for the out-off plane electronic second moment as additional input, reliable values can be given also for the individual components of the magnetic susceptibility tensor and for the bulk susceptibility:

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The Molecular Zeeman Effect of Imines. I. Methanimine, its Molecular g-Tensor, its Magnetic Susceptibility Anisotropies, its Molecular Electric Quadrupole Moment, its Electric Field Gradient at the Nitrogen Nucleus, and its Nitrogen Spin-Rotation Coupling