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Syntheses, properties, structure aspects and reactivity of non- and aromatically carbo- and heterocyclic annulated  1H - and  3H -1,3-azaphospholes are compared to illuminate the impact of annulation, substituent effects, aromatic stabilization and π-excess at phosphorus of the  1H -isomers, to demonstrate the current knowledge and open questions in this field of research.

π-Excess-aromatic and non-aromatic 1,3-azaphospholes – impact of annulation and multiple reactivity