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C 21 H 20 N 2 O 2 S, monoclinic,  P 2 1 / c  (no. 14),  a  = 19.436(3) Å,  b  = 6.1396(6) Å,  c  = 16.362(3) Å,  β  = 108.100(16)°,  V  = 1855.8(5) Å 3 ,  Z  = 4,  R  gt ( F ) = 0.0502,  wR  ref ( F  2 ) = 0.1224,  T  = 100 K.

The crystal structure of ( E )- N -benzyl- N′ -benzylidene-4-methylbenzenesulfonohydrazide, C 21 H 20 N 2 O 2 S