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Ca 5 N 5 V, orthorhombic,  Pbcm  (no. 57),  a  = 6.0371(3)  Å,  b  = 16.6146(7)  Å,  c  = 6.7815(3)  Å,  V  = 680.21(5)  Å 3 ,  Z  = 4,  R(P)  = 0.0100,  R F (all)  = 0.0348,  T  = 293 K.

Crystal structure of pentacalcium tetranitridovanadate(V) mononitride based on a powder diffraction study, Ca 5 [VN 4 ]N