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C 14 H 11 N 3 S orthorhombic,  Pbcn  (No. 60),  Z  = 8,  a  = 19.8130(12) Å,  b  = 8.1643(5) Å,  c  = 14.9521(9) Å,  V  = 2418.6(3) Å 3 ,  Z  = 8,  T  = 100(2) K,  GooF  = 1.055,  R  gt (F) = 0.0308,  wR  ref (F 2 ) = 0.0845.

Crystal structure of 2-(9H-fluoren-9-ylidene)hydrazine-1-carbothioamide, C 14 H 11 N 3 S