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The new heteropolyoxometalate compound (C 6 H 8 N) 5 [HAs 2 Mo 6 O 26 (H 2 O)]·3H 2 O: crystal structure and Hirshfeld surface analysis
Author(s) -
Harchani Ali,
Trzybiński Damian,
Pawlędzio Sylwia,
Woźniak Krzysztof,
Haddad Amor
Publication year - 2018
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229618012317
Subject(s) - monoclinic crystal system , crystallography , crystal structure , x ray crystallography , crystal (programming language) , diffraction , intermolecular force , chemistry , materials science , molecule , physics , optics , organic chemistry , programming language , computer science
A detailed description of the crystal structure and a Hirshfeld surface analysis of the new heteropolyoxometalate compound (C 6 H 8 N) 5 [HAs 2 Mo 6 O 26 (H 2 O)]·3H 2 O are reported. The title compound was synthesized using solution methods and its structure was characterized by single‐crystal X‐ray diffraction. The investigated compound contains a new [HAs 2 Mo 6 O 26 (H 2 O)] 5− polyanion and crystallizes in the monoclinic space group P 2 1 / c . The crystallographic analysis provided an understanding of the architecture and structural features of the complex crystal lattice and the Hirshfeld surface analysis shed more light on the intermolecular interactions occurring in the crystal.