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A three‐dimensional Cd II coordination framework: poly[di‐μ 2 ‐aqua‐{μ 2 ‐1,4‐bis[(1 H ‐1,2,4‐triazol‐1‐yl)methyl]benzene‐κ 2 N 4 : N 4′ }di‐μ 3 ‐terephthalato‐κ 3 O : O ′: O ′′‐dicadmium(II)]
Author(s) -
Shen Hong
Publication year - 2014
Publication title -
acta crystallographica section c
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.304
H-Index - 17
ISSN - 2053-2296
DOI - 10.1107/s2053229614020610
Subject(s) - binodal , thermogravimetric analysis , photoluminescence , crystallography , fluorescence , spectroscopy , infrared spectroscopy , hydrothermal synthesis , hydrothermal circulation , elemental analysis , chemistry , single crystal , fluorescence spectroscopy , coordination polymer , solid state , crystal structure , materials science , inorganic chemistry , physics , phase diagram , phase (matter) , organic chemistry , optics , seismology , geology , optoelectronics , quantum mechanics
The title Cd II coordination polymer, [Cd(C 10 H 8 O 4 )(C 12 H 12 N 6 ) 0.5 (H 2 O)] n , has been obtained by the hydrothermal method and studied by single‐crystal X‐ray diffraction, elemental analysis, thermogravimetric analysis, IR spectroscopy and fluorescence spectroscopy. The compound forms a novel three‐dimensional framework with 3,8‐connected three‐dimensional binodal {4.5 2 } 2 {4 2 .5 10 .6 12 .7.8 3 } topology. An investigation of its photoluminescence properties shows that the compound exhibits a strong fluorescence emission in the solid state at room temperature.
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