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In the title complex, [Cd 2 (CH 3 COO) 2 Cl 2 (C 16 H 14 N 4 )(CH 3 OH) 2 ]  n  , the Cd II  atom is six-coordinated by one N atom from a centrosymmetric bridging 1,2-bis­(2,2′-1 H -benzimidazol-2-yl)ethane (bbe) ligand, two O atoms from a chelating acetate ligand, one O atom from a methanol mol­ecule and two bridging Cl atoms in a distorted octa­hedral geometry. The Cd II  atoms are connected alternately by the Cl atoms and bbe ligands, leading to a chain along [001]. These chains are further linked by O—H⋯O hydrogen bonds. Intra­chain N—H⋯O hydrogen bonds are observed.

acta crystallographica. section e

catena-Poly[[(acetato-κ2O,O′)(methanol-κO)cadmium(II)]-μ-[1,2-bis(1H-benzimidazol-2-yl)ethane]-κ2N3:N3′-[(acetato-κ2O,O′)(methanol-κO)cadmium(II)]-di-μ-chlorido]