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Mononuclear cobalt(III) complex with 2-[(3-aminopropyl)amino]ethanethiol (Hapaet), [Co(apaet) 2 ]ClO 4  ( 1 ) and the sulfinate complex, [Co(apaetO 2 ) 2 ]ClO 4  ( 2 ) were synthesized and characterized by measurements of the elemental analysis, infrared and electronic spectra (UV-vis-NIR), and temperature dependence of magnetic susceptibilities (4.5—300 K), and DFT calculations. X-Ray crystal structure analysis of  1  and  2  revealed an octahedral CoS 2 N 4  or Co(SO 2 ) 2 N 4  chromophore with  meridional  chelation of two apaet −  or apaetO 2 − . Conversion of  1  to the sulfinate complex  2  via the sulfenate complex was investigated by UV-vis spectra. Oxidation reaction of capsanthin with  1  was also examined.

Cobalt Thiolates with Organic N,N,S-Tridentate Ligand: Conversion of Thiolate Complex to Sulfinate Complex via Sulfenate