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The authors obtained two-phase samples of silver- and zinc-modified hydroxyapatite (AgHA, ZnHA) by liquid-phase deposition under microwave exposure; the main phase for all samples was hydroxyapatite Ca 5 (PO 4 ) 3 (OH) with hexagonal syngony. The parameters of the elementary lattice of HA were studied via X-ray phase analysis and confirmed the formation of solid substitutional solutions while modifying HA with silver and zinc ions. Solubility has been estimated at 20 ºC for a 0.9% NaCl solution; specific surface area and porosity have been estimated for ZnHA powders obtained in presence of aminoacids. Surface morphology and dispersiveness have been studied for AgHA and ZnHA powders. Hammett method helped to establish the presence of acidic and basic centers on the surface of ZnHA and AgHA. Koch biotesting showed HA, AgHA, and ZnHA acting as inhibitors thus affecting  E. coli  tested samples. HA, AgHA, and ZnHA powders can be recommended for medical purposes.

Microwave synthesis and study of physicochemical properties of hydroxyapatite modified with silver and zinc ions