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This work presents a molecular dynamics study of the propagation scenario of the crowdion complex initiated in the platinum crystal by means of atom or molecule bombardment with parallel and non-parallel orientations. The obtained results enable to conclude that the crowdion initiated by the Pt 2  molecule bombardment is significantly more effective for the mass transfer comparing to the crowdion excited by the single atom impact. It was detected that the atoms involved in the crowdion motion bear a vibrational mode with the frequency above the phonon spectrum. The obtained results contribute to the understanding of the mechanisms of mass transfer under equilibrium conditions.

Mass transfer in platinum by crowdion clusters initiated by the impact of a Pt2 molecule

Mass transfer in platinum by crowdion clusters initiated by the impact of a Pt₂ molecule