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The Zhu III Sub-basin is an important petroliferous basin in the Pearl River Mouth Basin. To obtain the evolution of liquid and gaseous hydrocarbon of the kerogen in the Zhu III Sub-basin, a sample of Wenchang formation in the sub-basin was used in the confined pyrolysis experiments in the present study. The results show that the kerogen has very good hydrocarbon generation potential, with the maximum ΣC 1 -C 5  and ΣC 6+  yields of 999.69ml/g·TOC and 808.71mg/g·TOC, respectively, at 600°C. To further study the process of the process of hydrocarbon generation in geological conditions of the sub-basin, the burial, temperature, and thermal history are reconstructed. The kerogen of Wenchang formation started to generate oil and gas at 37Ma and 25Ma, respectively. The transformation ratio value of ΣC 6+  reached 100% at 14.45Ma, and that of ΣC 1 -C 5  reached 37%, mainly ΣC 2 -C 5 , at present.

Modeling hydrocarbon generation of the Wenchang formation in Zhu III Sub-basin, Pearl River Mouth Basin South China by confined pyrolysis