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Previous research demonstrated that a small amount of nickel enhances the coloration efficiency of tungsten-nickel oxide electrochromic (EC) thin films with respect to that of pure tungsten oxide (WO3) films. Furthermore the incorporation of titanium gives an improvement in the durability of tungsten-titanium oxide EC thin films. In this work we investigated the EC performance of tungsten-nickel-titanium oxide (W1-x-yNixTiyO3) EC thin films with emphasis on durability. The films were deposited on indium tin oxide covered glass by reactive dc sputtering from tungsten, tungsten-titanium alloy and nickel targets. Cyclic voltammetry was performed using 1 M LiClO4 in propylene carbonate as electrolyte. The voltage window was chosen to induce fast degradation of the samples within 80 cycles. Elemental compositions were obtained by Rutherford Backscattering Spectroscopy

Sputter deposited W1–x–yNixTiyO3thin films: Electrochromic properties and durability

Sputter deposited W_1–x–yNi_xTi_yO₃thin films: Electrochromic properties and durability