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The magnetic properties of the compound [Mn3L4](C1O4)2(H2O)2 revealed that it is a rare trinuclear MnII compound showing ferromagnetic interactions and a possible anisotropic behaviour. Here we report preliminary magnetic susceptibility measurements and spin density determinations at the Mn and O atoms to elucidate the magnetic interaction model and the possible anomalous anisotropic magnetic behaviour reported previously for this compound, that it is confirmed to be inexistent.This work has been funded by the Spanish MICINN and FEDER, Projects MAT2007-61621, MAT2009-13977-C03-01, and CSD2007-00010. C Rodríguez-Blanco acknowledges the “Europe Program” of CAI and Aragón Government for financial support.Peer Reviewe

journal of physics. conference series

Spin delocalization in the molecular manganese tetra-helicate cluster: [Mn3L4](ClO4)2(H2O)2