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The transition metal Mn 2+  ions doped materials have been widely reported for the luminescent properties for its broad emission band from green to red due to the spin-forbidden  4 T 1 → 6 A 1  transitions. To investigate the luminescent properties of Mn 2+  ions in cuspidine glass, the 3CaO-CaF 2 -2SiO 2  glasses doped with different Mn 2+  concentration were prepared with traditional melt-quenching method. The luminescence emission spectra, excitation spectra and luminescence decay curves were recorded and analyzed. The tunable broadband emission from orange to red was obtained. The luminescence intensity and lifetime of Mn 2+ :  4 T 1  level showed different quenching points with the increasing of Mn 2+  concentration. All these results indicate that Mn 2+  doped 3CaO-CaF 2 -2SiO 2  glass could be applied as light conversion material for solid-state lighting applications.

Luminescent Properties of a Novel Mn2+ doped 3CaO-CaF2-2SiO2 Glasses

Luminescent Properties of a Novel Mn²⁺ doped 3CaO-CaF₂-2SiO₂ Glasses