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Blast furnace (BF) slag, one of the by-products of iron- and steel-making plants, was converted into the product including hydrogrossular and hydroxysodalite using the alkali fusion method for HCl gas fixation. The slag was transformed into the alkali-fused slag with reactive phases via alkali fusion, after which the fused slag was added to distilled water with Al(OH) 3  to synthesize the product including a hydrogrossular by heating at 120°C for 24 h. The product including hydrogrossular, hydroxysodalite and calcite can be synthesized with addition of Al(OH) 3 , and could remove HCl gas at high temperature to fix Cl in the product. These results suggest that a novel product able to fix HCl gas at high temperature can be synthesized from BF slag via alkali fusion.

Synthesis of hydrogrossular and hydroxysodalite from blast furnace slag using alkali fusion for fixation of HCl gas