Open AccessControl of dominant conduction orbitals by peripheral substituents in paddle-wheel diruthenium alkynyl molecular junctions
Author(s) -
Shiori Ogawa,
Swarup Chattopadhyay,
Yuya Tanaka,
Tatsuhiko Ohto,
Tomofumi Tada,
Hayato Tada,
Shintaro Fujii,
Tomoaki Nishino,
Munetaka Akita
Publication year - 2021
Publication title -
chemical science
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 3.687
H-Index - 172
eISSN - 2041-6539
pISSN - 2041-6520
DOI - 10.1039/d1sc02407h
Subject(s) - homo/lumo , conductance , substituent , chemistry , molecular orbital , cyclic voltammetry , atomic orbital , crystallography , molecule , computational chemistry , stereochemistry , electron , electrochemistry , condensed matter physics , physics , organic chemistry , quantum mechanics , electrode
Dominant conduction orbitals of paddle-wheel organodiruthenium complexes can be facilely controlled by the substituents embedded in the amidinato ligands.