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Herein we demonstrate the effect that the structure of olefinic end-group ( i.e.  oxanorbornenyl vs norbornenyl) has upon the outcome of both macromonomer preparation by RAFT polymerization and subsequent bottlebrush polymer synthesis by ROMP.

Effect of radical copolymerization of the (oxa)norbornene end-group of RAFT-prepared macromonomers on bottlebrush copolymer synthesis via ROMP