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2-Amino-1,8-naphthalimide showed blue fluorescence independent of the microenvironment of the solvents whereas the corresponding 3- and 4-amino derivatives displayed marked positive solvatofluorochromism.

photochemical and photobiological sciences

Fluorescence behaviour of 2-, 3- and 4-amino-1,8-naphthalimides: effects of the substitution positions of the amino functionality on the photophysical properties