Open AccessRecent Advances in the Construction of Fluorinated Organoboron Compounds
Author(s) -
Xingxing Ma,
Zhijie Kuang,
Qiuling Song
Publication year - 2021
Publication title -
jacs au
Language(s) - English
Resource type - Journals
ISSN - 2691-3704
DOI - 10.1021/jacsau.1c00129
Subject(s) - organoboron compounds , borylation , chemistry , moiety , combinatorial chemistry , organic chemistry , boron , alkyl , aryl
Fluorinated organoboron compounds are important synthetic building blocks that combine the unique characteristics of a fluorinated motif with the versatile synthetic applications of organoboron moiety. This review article guides the research on fluorinated organoboron compounds mainly from four aspects in recent years: selective monodefluoroborylation of polyfluoroarenes and polyfluoroalkenes, selective borylation of fluorinated substrates, selective fluorination of organoboron compounds, and borofluorination of alkynes/olefins. In addition, this review will provide a necessary guidance and inspiration for the research on the valuable synthetic building block fluorinated organoboron compounds.