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Spent anode graphite, a hazardous solid waste discarded from the recovery of spent lithium-ion batteries (LIBs), had created social and environmental issues but has been scarcely investigated. Thus, a feasible, environmentally friendly, and economical process of low-temperature fluorination roasting and water leaching technology was proposed to regenerate spent graphite anodes. The results showed that the physical and chemical properties of regenerated graphite with a purity of 99.98% reached the graphite anode standard of LIBs and exhibited a stable specific capacity (340.9 mAh/g), capacity retention (68.92% after 470th cycles), and high initial Coulombic efficiency (92.13%), much better than that of waste carbon residue and similar to that of commercial graphite. Then the reaction mechanism and kinetic modeling of fluorination roasting of spent anode material was mainly explored by differential thermogravimetry and nonisothermal analysis methods. The results showed that the complexation and phase-transformation process of non-carbon valuable components in spent anode graphite occurred through three consecutive reactions in the 80-211 °C temperature intervals. The reaction mechanism of the whole process can be kinetically characterized by three successive reactions: third-order chemical reaction, Z-L-T eq, and second-order chemical reaction. Moreover, the thermodynamic functions of the fluorination roasting were calculated by the activated complex theory (transition state), which indicated the process was nonspontaneous. The mechanistic information was in good agreement with thermogravimetric-infrared spectroscopy (TG-IR), electron probe microanalysis, scanning electron microscopy, energy-dispersive spectrometry, and simulation experiments results.

A Novel Low-Temperature Fluorination Roasting Mechanism Investigation of Regenerated Spent Anode Graphite via TG-IR Analysis and Kinetic Modeling