Open AccessEfficient Synthesis of α-FeOOH from Pickling Wastewater in Falling Film Tower and Its Kinetics
Author(s) -
Jian Chen,
Xiang Fang,
Min Zhu,
Junfeng Li,
Hongjun Yang,
Yuanyuan Che,
Zhipeng Mao
Publication year - 2021
Publication title -
acs omega
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.779
H-Index - 40
ISSN - 2470-1343
DOI - 10.1021/acsomega.1c00125
Subject(s) - pickling , tower , wastewater , falling (accident) , kinetics , materials science , reaction rate constant , chemical engineering , chemistry , waste management , metallurgy , physics , engineering , structural engineering , medicine , environmental health , quantum mechanics
An efficient way to synthesize α-FeOOH from pickling wastewater in a falling film tower was proposed for the first time. This method overcomes the shortcomings of the traditional air oxidation method, and its production efficiency is increased by 16 times. The purity of α-FeOOH synthesized from pickling wastewater can reach 96.3%, and the iron recovery rate is greater than 90%. At the same time, we have systematically studied its kinetics in the falling film tower. The reaction rate constant k at different temperatures was also determined with the activation energy E a = 32.2497 kJ/mol and the pre-exponential A = 47.4132 s -1 . In addition, based on the double-film theory, a corresponding macrokinetic model was established. Also, the Hatta number in the reaction system was obtained, which proved the excellent gas-liquid mass transfer performance in the falling film tower. This work provides a promising method for the efficient production of α-FeOOH and the recycling of pickling wastewater.