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Combining hydraulic fracturing with lateral drilling has allowed for economical hydrocarbon production from unconventional formations. Nevertheless, beyond hydraulic fracturing, our understanding of how hydrocarbons are stored and transported from the stimulated volume of a reservoir is still limited. Source rocks consist of organic materials finely dispersed within an inorganic matrix. Despite their small size, these organic pockets are capable of storing significant amounts of hydrocarbon due to their large surface area. The extent of the source rock's storage capacity is determined by several factors, including the natural fracture abundancy, organic material content, type, and level of maturity. The petrophysical properties of organic materials, also known as kerogens, are subject to a high degree of uncertainty. Kerogens are difficult to isolate experimentally, which hinders accurate petrophysical analysis. The objective of this research was to use a molecular modeling approach to explore the petrophysical characteristics of kerogen. Kerogen macromolecules of different types and maturity levels were recreated via a computational platform. Then nanoporous structures representing these kerogens were obtained and characterized. Several elemental parameters, including porosity, density, pore size distribution, and adsorption capacity were closely delineated. The kerogen properties were found to correlate with the kerogen type and thermal maturity level. Kerogen type III showed the highest storage capacity, followed by types II and I, in a descending order. Moreover, in the same type of kerogen, a general trend of increasing storage capacity was observed as the maturity level increased. Methane adsorption capacity was modeled as a function of kerogen porosity. A transition flow regime was found to be the predominant mechanism. Such observations have significant implications for reservoir-scale modeling of unconventional resources.

Petrophysics of Kerogens Based on Realistic Structures