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Synthesis of 1,1,1‐Tris(2‐hydroxyethyl)amine‐2‐acylimide
Author(s) -
Ikeda Isao,
Katsura Tadashi F.,
Okahara Mitsuo
Publication year - 1976
Publication title -
journal of the american oil chemists' society
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.512
H-Index - 117
eISSN - 1558-9331
pISSN - 0003-021X
DOI - 10.1007/bf02586255
Subject(s) - hydrazine (antidepressant) , hydrate , ethylene oxide , tris , molar ratio , chemistry , yield (engineering) , amine gas treating , solvent , ethylene , amine oxide , nuclear chemistry , organic chemistry , polymer chemistry , inorganic chemistry , catalysis , materials science , chromatography , copolymer , polymer , biochemistry , alkyl , metallurgy
Abstract 1,1,1‐Tris(2‐hydroxyethyl)amine‐2‐acylimide (I) was prepared by the reaction of hydrazine hydrate, ethylene oxide, and fatty acid methyl ester. Reaction conditions such as solvent, reaction temperature, and molar ratio of reactants were investigated, and (I) was obtained in 73% yield by heating an isopropanol solution of hydrazine hydrate, methyl palmitate, and ethylene oxide in molar ratio of 1:6:6 at 80 C for 2 hr.