Cluster Helix Structure of the Binary Compound W 5 I 12 | Zendy

Ströbele Markus | Zendy; Meyer H.Jürgen | Zendy

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Cluster Helix Structure of the Binary Compound W 5 I 12

Author(s) -

Ströbele Markus,

Meyer H.Jürgen

Publication year - 2016

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201600131

Subject(s) - crystallography , crystal structure , chemistry , iodide , cluster (spacecraft) , group (periodic table) , tungsten , diffraction , physics , inorganic chemistry , computer science , optics , organic chemistry , programming language

The binary tungsten iodide W 5 I 12 forms an unprecedented one‐dimensional helical structure. A crystal structure refinement performed on basis of X‐ray powder diffraction data revealed the space group P6 1 [Z = 6, a = 993.97(2) pm, c = 4226.73(9) pm]. The crystal structure is based on [(W 5 I 8 i )I 3 a I 2/2 a‐a ] clusters, interconnected by two shared apical iodido ligands to form helical chain arrangements.

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