Thiodipropionate Zn II  Complexes: Synthesis, DFT Studies, and X‐ray Structure of [{Zn(phen)(H 2 O)} 2 (μ‐tdp) 2 ]·3H 2 O | Zendy

Grirrane Abdessamad | Zendy; Álvarez Eleuterio | Zendy; Pastor Antonio | Zendy; Galindo Agustín | Zendy

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Thiodipropionate Zn II Complexes: Synthesis, DFT Studies, and X‐ray Structure of [{Zn(phen)(H 2 O)} 2 (μ‐tdp) 2 ]·3H 2 O

Author(s) -

Grirrane Abdessamad,

Álvarez Eleuterio,

Pastor Antonio,

Galindo Agustín

Publication year - 2010

Publication title -

zeitschrift für anorganische und allgemeine chemie

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.354

H-Index - 66

eISSN - 1521-3749

pISSN - 0044-2313

DOI - 10.1002/zaac.201000145

Subject(s) - zinc , chemistry , crystallography , x ray , aqueous solution , ion , inorganic chemistry , physics , organic chemistry , quantum mechanics

The zinc thiodipropionate complex [Zn(tdp)] ( 1 ) [tdp = S(CH 2 CH 2 COO) 2 2– ] was obtained by reaction of aqueous zinc dichloride with a 1:1 mixture of Na 2 CO 3 and thiodipropionic acid. The bonding preferences of the tdp anion were studied by DFT methods. The reaction of 1 with o ‐phenanthroline (phen) gave the dinuclear compound [{Zn(phen)(H 2 O)} 2 (μ‐tdp) 2 ] · 3H 2 O ( 2 ), which was characterized by X‐ray analysis.

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