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Synthesis and properties of the orthometallated rhodium complex Rh{P(OPh) 3 } 3 {P(OC 6 H 4 )(OPh) 2 }
Author(s) -
Trzeciak Anna M.,
Ziołkowski Jozef J.
Publication year - 1989
Publication title -
zeitschrift für anorganische und allgemeine chemie
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.354
H-Index - 66
eISSN - 1521-3749
pISSN - 0044-2313
DOI - 10.1002/zaac.19895770129
Subject(s) - rhodium , chemistry , reactivity (psychology) , stereochemistry , medicinal chemistry , crystallography , catalysis , organic chemistry , medicine , alternative medicine , pathology
Abstract The orthometallated complex formulated as Rh{P(OPh) 3 } 3 {P(OC 6 H 4 )(OPh) 2 } ( 1 ) was obtained in the reaction between [Rh(OCH 3 )(cod)] 2 and P(OPh) 3 . Based on the 31 PNMR and UV‐VIS results the alternative structure of that compound — Rh{P(OPh) 3 } 3 {P(O)(OPh) 2 } ( 2 ) — was discussed. Both — the formation process of that compound and its reactivity allow to regard it as the orthometallated complex ( 1 ).