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Host–guest chemistry in the gas phase. Complexes of crown ethers with Fe(CO) n + ions
Author(s) -
Gren' A. I.,
Mazepa A. V.,
Timofeev O. S.
Publication year - 1995
Publication title -
rapid communications in mass spectrometry
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.528
H-Index - 136
eISSN - 1097-0231
pISSN - 0951-4198
DOI - 10.1002/rcm.1290090923
Subject(s) - chemistry , crown ether , reagent , ring (chemistry) , ring size , ether , bicyclic molecule , ion , crown (dentistry) , gas phase , 18 crown 6 , inorganic chemistry , organic chemistry , polymer chemistry , medicinal chemistry , medicine , dentistry
Abstract The complexes formed between a series of 19 different crown ethers and Fe(CO) n +ions are described. It is found that the energy released in the reactions increases with the crown ether ring size. The bicyclic‐ring crown ethers can form sandwich type compounds with the reagent.