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Scanning tunneling microscopy (STM) investigations on two hexaboride compounds, SmB 6  and EuB 6 , are compared in an effort to provide a comprehensive picture of their surface structural properties. The latter is of particular importance for studying the nature of the surface states in SmB 6  by surface‐sensitive tools. Beyond the often encountered atomically rough surface topographies of in situ, low‐temperature cleaved samples, differently reconstructed as well as B‐terminated and, more rarely, rare‐earth terminated areas can be found. With all the different surface topographies observed on both hexaborides, a reliable assignment of the surface terminations is brought forward.

Comparative Scanning Tunneling Microscopy Study on Hexaborides