Open AccessReactivity of Ionic Liquids: Reductive Effect of [C 4 C 1 im]BF 4 to Form Particles of Red Amorphous Selenium and Bi 2 Se 3 from Oxide Precursors
Author(s) -
Knorr Monika,
Schmidt Peer
Publication year - 2021
Publication title -
chemistryopen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 29
ISSN - 2191-1363
DOI - 10.1002/open.202000264
Subject(s) - ionic liquid , reactivity (psychology) , differential scanning calorimetry , selenium , tetrafluoroborate , amorphous solid , reducing agent , chemistry , decomposition , characterization (materials science) , chalcogen , oxide , thermal decomposition , ionic bonding , inorganic chemistry , crystallography , materials science , catalysis , nanotechnology , organic chemistry , medicine , physics , alternative medicine , pathology , thermodynamics , ion
Abstract Temperature‐induced change in reactivity of the frequently used ionic liquid 1‐butyl‐3‐methylimidazolium tetrafluoroborate ([C 4 C 1 im]BF 4 ) is presented as a prerequisite for the rational screening of reaction courses in material synthesis. [C 4 C 1 im]BF 4 becomes active with oxidic precursor compounds in reduction reaction at ϑ ≥200 °C, even without the addition of an external reducing agent. The reaction mechanism of forming red amorphous selenium from SeO 2 is investigated as a model system and can be described similarly to the Riley oxidation. The reactive species but‐1‐ene, which is formed during the decomposition of [C 4 C 1 im]BF 4 , reacts with SeO 2 and form but‐3‐en‐2‐one, water, and selenium. Elucidation of the mechanism was achieved by thermoanalytical investigations. The monotropic phase transition of selenium was analyzed by the differential scanning calorimetry. Beyond, the suitability of the single source oxide precursor Bi 2 Se 3 O 9 for the synthesis of Bi 2 Se 3 particles was confirmed. Identification, characterization of formed solids succeeded by using light microscopy, XRD, SEM, and EDX.