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The syntheses of tris(organostannyl)methanes HC(SnX  n  Ph (3‐ n ) ) 3  ( 1 ,  n =0;  2 ,  n =1, X=I;  3 ,  n =1, X =F;  4 ,  n =1, X=Cl;  5 ,  n =1, X=OAc;  6 ,  n =2, X=I;  7 ,  n =2, X=Cl) and the organostannate complexes Et 4 N[HC(SnIPh 2 ) 3 ⋅F] ( 8 ), Ph 4 P[HC(SnClPh 2 ) 3 ⋅Cl] ( 9 ), and [Ph 4 P] 2 [HC(SnCl 2 Ph) 3 ⋅2 Cl] ( 10 ) are reported. The compounds were characterized by  1 H,  13 C,  19 F, and  119 Sn NMR spectroscopy, IR spectroscopy, electrospray mass spectrometry, and (with the exception of  3 ) single‐crystal X‐ray diffraction analysis. From the reaction between  2  and AgClO 4  resulted the unprecedented hexanuclear organotin oxocluster [HC{Sn(ClO 4 ) 2 Ph 2 } 2 Sn(OH) 2 Ph] 2  ( 11 ), the molecular structure of which was elucidated by using X‐ray crystallography.

Syntheses, Structures, and Complexation Studies of Tris(organostannyl)methane Derivatives