Open AccessA Ferrocenyl‐Backboned Unsymmetric O,C‐Coordinating Ligand and Its Tin Derivatives
Author(s) -
Janssen Bastian,
Lutter Michael,
Alnasr Hazem,
Krossing Ingo,
Jurkschat Klaus
Publication year - 2016
Publication title -
chemistryopen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 29
ISSN - 2191-1363
DOI - 10.1002/open.201600048
Subject(s) - chemistry , tin , ligand (biochemistry) , derivative (finance) , electrospray ionization , stannane , ferrocene , mass spectrometry , electrospray mass spectrometry , crystallography , medicinal chemistry , electrospray , organic chemistry , electrochemistry , biochemistry , receptor , electrode , chromatography , financial economics , economics
The syntheses of the phosphonyl‐substituted ferrocenyl stannane Fe[{ η 5 ‐C 5 H 3 ‐1‐SnPh 3 ‐2‐P(O)(O‐ i Pr) 2 }{ η 5 ‐C 5 H 4 P(O)(O‐ i Pr) 2 }] ( 1 ) and its iodine derivative Fe[{ η 5 ‐C 5 H 3 ‐1‐SnPh 2 I‐2‐P(O)(O‐ i Pr) 2 }{ η 5 ‐C 5 H 4 P(O)(O‐ i Pr) 2 }] ( 2 ) are reported. The syntheses of the corresponding salts Fe[{ η 5 ‐C 5 H 3 ‐1‐SnPh 2 ‐2‐P(O)(O‐ i Pr) 2 }{ η 5 ‐C 5 H 4 P(O)(O‐ i Pr) 2 }]X ( 3 , X=Al{OC(CF 3 ) 3 } 4 , 4 , X=ClO 4 , 5 , X=HgI 3 ), respectively, are also described. The compounds are characterized by elemental analyses, 1 H, 13 C, 31 P, 119 Sn NMR and IR spectroscopy, electrospray ionization mass spectrometry, and, except for 4 and 5 , single‐crystal X‐ray diffraction analyses.