Open AccessSystematic Studies on 3 d‐ and 4 f‐Metal Containing Polyoxometalates Suitable for Organic Derivatization
Author(s) -
Artetxe Beñat
Publication year - 2016
Publication title -
chemistryopen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 29
ISSN - 2191-1363
DOI - 10.1002/open.201500221
Subject(s) - polyoxometalate , derivatization , chemistry , transition metal , electrophile , denticity , metal , surface modification , polymer chemistry , catalysis , mass spectrometry , organic chemistry , chromatography
Premium polyoxometalates ! The organic functionalization of 3 d‐metalsubstituted polyoxometalates and the synthesis of new metal‐oxo clusters with accessible 3 d‐ and 4 f‐metal centers suitable for organic derivatization are discussed in this thesis. A total number of 39 compounds were structurally characterized, and their luminescent and magnetic properties analyzed. The solution behavior was studied by NMR spectroscopy, mass spectrometry, and light‐scattering techniques.