Open AccessMetallacycles Capabilities in Host–Guest Chemistry
Author(s) -
PonceVargas Miguel
Publication year - 2015
Publication title -
chemistryopen
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.644
H-Index - 29
ISSN - 2191-1363
DOI - 10.1002/open.201500125
Subject(s) - multipole expansion , quadrupole , host (biology) , dipole , metallacycle , nanoclusters , representation (politics) , chemistry , quadrupole magnet , nanotechnology , chemical physics , computational chemistry , physics , materials science , atomic physics , organic chemistry , quantum mechanics , ecology , x ray crystallography , politics , political science , diffraction , law , biology
The perfect host for anions ! The nature of host–guest interactions in metallacycle‐based complexes was determined by various methodologies. Additionally, by plotting the atomic multipole moment tensors, a clear representation of the higher‐order electrostatic interactions within the studied systems, such as dipole–quadrupole and quadrupole–quadrupole forces, was obtained.